11 Group 14
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Candidates should be able to:
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11.1 Physical properties of Group 14 elements
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(a) explain the trends in physical properties (melting points and electrical conductivity) of Group 14 elements: C, Si, Ge, Sn, Pb.
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11.2 Tetrachlorides and oxides of Group 14 elements
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(a) explain the bonding and molecular shapes of the tetrachlorides of group 14 elements; (b) explain the volatility, thermal stability and hydrolysis of tetrachlorides in terms of structure and bonding; (c) explain the bonding, acid-base nature and the thermal stability of the oxides of oxidation states +2 and +4.
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11.3 Relative stability of +2 and +4 oxidation states of Group 14 elements
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(a) explain the relative stability of +2 and +4 oxidation states of the elements in their oxides, chlorides and aqueous cations.
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11.4 Silicon, silicone and silicates
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(a) describe the structures of silicone and silicates (pyroxenes and amphiboles), sheets (mica) and framework structure (quartz) (general formulae are not required);
(b) explain the uses of silicon as a semiconductor
and silicone as a fluid, elastomer and resin;
(c) describe the uses of silicates as basic materials
for cement, glass, ceramics and zeolites.
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11.5 Tin alloys
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(a) describe the uses of tin in solder and pewter.
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*Not suggest to copy down all of them, just for reference in doing own notes
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